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Seasonal changes in snow water equivalent and chemical properties on Gourlay Snowfield and Tuva Glacier, Signy Island, Antarctica, 2012-2013

Between December 2012 and March 2013, snow measurements were conducted at both Gourlay Snowfield and Tuva Glacier, Signy Island. Sites are denoted 'TX' and 'GY', where 'X' and 'Y' are numbers representing one of nine snowpits in a grid at Tuva and Gourlay respectively. Measurements include snow water equivalent and chemical properties.





Snow thickness was measured during the surveys (and opportunistically following fresh snowfall events) at all 18 snow pits using an avalanche probe (average of 3 readings per sampling site). Snow density was also assessed at each site using a 1L pvc. snow tube. The thickness of the superimposed ice was measured at the beginning and at the end of the season after excavation using an ice axe. In order to calculate the proportion of the total winter accumulation that was transformed into superimposed ice by refreezing, its density was assumed to be 0.9 kg L-1.





Three surveys at each of the 18 sites were conducted for biogeochemical conditions: 'top' refers to the upper 20cm; 'mid' refers to the rest of the snow; and 'ice' is the basal ice (refrozen snowmelt on top of last summer's surface). Key chemical properties determined include pH, dissolved organic carbon, total dissolved inorganic carbon, ammonium, chlorophyll and major ions.





Funding was provided by the NERC grants NE/H014446/1 and NE/H014802/1.

Simple

Date (Creation)
2017-03-09
Date (Revision)
2017-03-09
Date (Publication)
2017-03-09
Date (released)
2017-03-09
Edition

1

Unique resource identifier
https://doi.org/10.5285/18ff2b3c-ba0c-4b5b-83b4-79b0d978aa66
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doi

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GB/NERC/BAS/PDC/00928
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https://data.bas.ac.uk/

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NE/H014446/1
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award

Unique resource identifier
NE/H014802/1
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Please cite this item as: None

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Completed
Point of contact
Organisation name Individual name Electronic mail address Role

University of Sheffield

Hodson, Andy

Author
British Antarctic Survey

Pearce, David

Author

University of Bristol

Sabacka, Marie

Author
British Antarctic Survey

Convey, Pete

Author
NERC EDS UK Polar Data Centre

PDCServiceDesk@bas.ac.uk

Point of contact
Maintenance and update frequency
As needed
Maintenance note
Completed
Global Change Master Directory (GCMD) Science Keywords
  • EARTH SCIENCE > Cryosphere > Glaciers/Ice Sheets > Glaciers
  • EARTH SCIENCE > Cryosphere > Glaciers/Ice Sheets > Ice Sheets
  • EARTH SCIENCE > Cryosphere > Snow/Ice > Snow/Ice Chemistry
Theme
  • Biogeochemistry

  • Glacier

  • Signy Island

  • Snow

Place
  • Gourlay Snowfield and Tuva Glacier, Signy Island Antarctica

GEMET - INSPIRE themes, version 1.0

  • Elevation
  • Meteorological geographical features
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no limitations to public access
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Open Government Licence v3.0
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This data is governed by the NERC Data Policy: https://www.ukri.org/who-we-are/nerc/our-policies-and-standards/nerc-data-policy/

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This data is governed by the NERC data policy and supplied under Open Government Licence v.3

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Requests for data can be made via the UK Polar Data Centre (UK PDC) at BAS.

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Language
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  • Climatology, meteorology, atmosphere
  • Environment
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Begin date
2012-12-11
End date
2013-03-12
Supplemental Information

It is recommended that careful attention be paid to the contents of any data, and that the author be contacted with any questions regarding appropriate use. If you find any errors or omissions, please report them to polardatacentre@bas.ac.uk.

Title

European Petroleum Survey Group (EPSG) Geodetic Parameter Registry

Date (Publication)
2008-11-12
Cited responsible party
Organisation name Individual name Electronic mail address Role

European Petroleum Survey Group

EPSGadministrator@iogp.org

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Unique resource identifier
urn:ogc:def:crs:EPSG::3031
Version

6.18.3

Distributor

Distributor contact
Organisation name Individual name Electronic mail address Role
NERC EDS UK Polar Data Centre

PDCServiceDesk@bas.ac.uk

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1
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WWW:LINK-1.0-http--link

https://ramadda.data.bas.ac.uk/repository/entry/show/?entryid=18ff2b3c-ba0c-4b5b-83b4-79b0d978aa66

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Methodology:

The pH was determined using standard, portable meter and electrodes (Hanna Instruments, UK) calibrated using fresh pH 4 and 7 buffers. The other parameters required analysis of a filtered sample, which was undertaken immediately after melting. For both DOC and TDIC, a 50mL aliquot was filtered through a Whatman GFF filter paper (notional pore space: 0.7 µm) and stored in pre-rinsed 40 mL glass vials for DOC analyses using the membrane conductometric method. This employed a Sievers 5310 Analyser with UV and persulphate digestion (detection limit 0.01 mg L-1 and < 5% precision errors according to repeat analysis of mid-range (0.4 mg L-1) standards.





For NH4+ we employed the fluorescence technique described by Taylor et al (2007), using a Turner Instruments Aquafluor fluorometer, with a 375 nm excitation LED and a 420 nm long pass filter for emission detection. The samples were incubated for typically three to five hours in order to optimise the intensity of the fluorescence and enable a detection limit of 0.1 µg L-1. The same device was also used to provide an optical measure of the abundance of fluorescent DOC in the filtered samples. Untreated samples were allowed to equilibrate to room temperature and the average of three fluorescence readings taken at the same wavelengths used for the NH4+ detection. These excitation/emission wavelengths are used as an industry standard for the detection of chromophoric dissolved organic matter or 'CDOM' and readings are used here to assess whether there were any changes in the source of the DOC.





Melted snow or ice (300-900 mL) was filtered under low pressure onto 25 mm GF/F filters (combusted at 450°C for 5 hours). All sample and filter handling was conducted under low light and low temperature conditions and in an acid-free environment. Filters were stored in glassine envelopes in -80°C until further analysis (1-8 weeks). Filters were then added to clean glass scintillation vials with 10 ml of 80% methanol for extraction. Chlorophyll-a standards (Anacystis nidulans, Sigma) were made just prior to analysis (0, 1, 2, 5, 10, 50, 100, 200, 500 and 1000 µg L-1). Triplicate measurements were conducted using the Turner Designs Aquafluor fluorometer with excitation at 395 + 65 nm. The accuracy was tested by repeated use of blanks, chlorophyll standards and a solid standard.





Samples from the first survey at each site were also subject to analysis after 0.45 µm filtration (WCN paper) to ion chromatography, with a detection limit of 1 ppb and precision errors of 5% or better on mid-range calibration solutions.

Data collection:

Instruments used include:



Turner Instruments Aquafluorometer



Sievers 5310 Analyser



Dionex DX90



Apogee SQ100 pyranometer

Metadata

File identifier
18ff2b3c-ba0c-4b5b-83b4-79b0d978aa66 XML
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English
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UTF8
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Dataset
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dataset

Date stamp
2017-03-09
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ISO 19115 Geographic Information - Metadata

Metadata standard version

ISO 19115:2003(E)

Metadata author
Organisation name Individual name Electronic mail address Role
NERC EDS UK Polar Data Centre

polardatacentre@bas.ac.uk

Point of contact
 
 

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Keywords

Biogeochemistry Glacier Signy Island Snow
GEMET - INSPIRE themes, version 1.0

Elevation Meteorological geographical features
Global Change Master Directory (GCMD) Science Keywords

EARTH SCIENCE > Cryosphere > Glaciers/Ice Sheets > Glaciers EARTH SCIENCE > Cryosphere > Glaciers/Ice Sheets > Ice Sheets EARTH SCIENCE > Cryosphere > Snow/Ice > Snow/Ice Chemistry


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