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Biogeochemistry and phytoplankton data from Loch Etive, Scotland, October 2022

This dataset contains biogeochemical measurements of surface water, sampled across Loch Etive, Scotland, between the 3rd and 7th of October 2022. The dataset encompasses 23 locations including nine open loch stations, four fish-farm adjacent loch sites, six river inflows, and four process experiment river sites, enabling a comparison of water chemistry across marine, freshwater, and anthropogenically influenced environments. Surface water samples were collected and analysed for an extensive range of biogeochemical parameters. In-field measurements included water temperature, pH, dissolved oxygen, and specific conductivity. Laboratory analyses comprised: - Alkalinity - Major nutrients, including nitrate, nitrite, ammonium, soluble reactive phosphorus (SRP), and silica - Dissolved and total organic and inorganic carbon and nitrogen (DOC, TIC, TDN) - Trace elements and rare earth elements (REEs), including lithium, barium, aluminium, and a full suite of lanthanides - Stable isotope composition of oxygen (δ18O), determined via isotope ratio mass spectrometry - Chromophoric and fluorescent dissolved organic matter (CDOM/FDOM), with derived indices such as fluorescence index (FI), biological index (BIX), and humification index (HIX) In addition to water chemistry, particulate samples were collected and analysed for total suspended solids (TSS), particulate organic matter (POM), particulate inorganic matter (PIM), chlorophyll-a concentration, and particulate organic carbon/nitrogen (POC/PON). Phytoplankton community composition was assessed by flow cytometry, quantifying major groups including diatoms, pico- and nano-chlorophytes, cryptophytes, and cyanobacteria. This comprehensive dataset is intended to inform biogeochemical process understanding in polar analogue environments and to validate analytical workflows and inter-institutional protocols. Full details about this dataset can be found at https://doi.org/10.5285/50f4344e-a79a-4e1f-a9ee-e7985ed847cd

Simple

Date (Publication)
2025-07-24
Citation identifier
https://catalogue.ceh.ac.uk/id/50f4344e-a79a-4e1f-a9ee-e7985ed847cd
Citation identifier
doi: / 10.5285/50f4344e-a79a-4e1f-a9ee-e7985ed847cd
Other citation details

Grant, A.L., Arrowsmith, C., Barry, C., Bowes, M.J., Callaghan, N., Eades, L.J., Fournier, I., Hendry, K., Mawji, E., O'Brien, A., Olszewska, J.P., Pickard, A.E., Tandy, S., Spears, B.M. (2025). Biogeochemistry and phytoplankton data from Loch Etive, Scotland, October 2022. NERC EDS Environmental Information Data Centre 10.5285/50f4344e-a79a-4e1f-a9ee-e7985ed847cd

Point of contact
Organisation name Individual name Electronic mail address Role
UK Centre for Ecology & Hydrology

Grant, A.

enquiries@ceh.ac.uk

Point of contact
UK Centre for Ecology & Hydrology Grant, A.L.

enquiries@ceh.ac.uk

Author
British Geological Survey Arrowsmith, C.

caar@bgs.ac.uk

Author
UK Centre for Ecology & Hydrology

Barry, C.

enquiries@ceh.ac.uk

Author
UK Centre for Ecology & Hydrology Bowes, M.J.

enquiries@ceh.ac.uk

Author
UK Centre for Ecology & Hydrology Callaghan, N.

enquiries@ceh.ac.uk

Author
University of Edinburgh

Eades, L.J.

Lorna.Eades@ed.ac.uk

Author
UK Centre for Ecology & Hydrology Fournier, I.

enquiries@ceh.ac.uk

Author
British Antarctic Survey Hendry, K.

kathen@bas.ac.uk

Author
National Oceanography Centre Mawji, E.

ezm@noc.ac.uk

Author
UK Centre for Ecology & Hydrology O'Brien, A.

enquiries@ceh.ac.uk

Author
UK Centre for Ecology & Hydrology Olszewska, J.P.

enquiries@ceh.ac.uk

Author
UK Centre for Ecology & Hydrology Pickard, A.E.

enquiries@ceh.ac.uk

Author
UK Centre for Ecology & Hydrology Tandy, S.

enquiries@ceh.ac.uk

Author
UK Centre for Ecology & Hydrology Spears, B.M.

enquiries@ceh.ac.uk

Author
UK Centre for Ecology & Hydrology

enquiries@ceh.ac.uk

Owner
NERC EDS Environmental Information Data Centre

info@eidc.ac.uk

Custodian
NERC EDS Environmental Information Data Centre

info@eidc.ac.uk

Publisher

GEMET - INSPIRE themes, version 1.0

  • Hydrography

GEMET - Concepts, version 4.1.3

  • biogeochemistry
  • chlorophyll
  • fish farming
  • isotope
  • metal
  • nutrient
  • river transport
  • water quality
Keywords
  • Water quality
  • Loch Etive

  • Scotland

Access constraints
Other restrictions
Other constraints
no limitations
Use constraints
Other restrictions
Other constraints
This resource is available under the terms of the Open Government Licence
Use constraints
Other restrictions
Other constraints

If you reuse this data, you should cite: Grant, A.L., Arrowsmith, C., Barry, C., Bowes, M.J., Callaghan, N., Eades, L.J., Fournier, I., Hendry, K., Mawji, E., O'Brien, A., Olszewska, J.P., Pickard, A.E., Tandy, S., Spears, B.M. (2025). Biogeochemistry and phytoplankton data from Loch Etive, Scotland, October 2022. NERC EDS Environmental Information Data Centre https://doi.org/10.5285/50f4344e-a79a-4e1f-a9ee-e7985ed847cd

Spatial representation type
Text, table
Language
English
Character set
UTF8
Topic category
  • Environment
Begin date
2022-10-03
End date
2022-10-07
N
S
E
W
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Unique resource identifier
OSGB 1936 / British National Grid
Distribution format
Name Version

Comma-separated values (CSV)

Distributor contact
Organisation name Individual name Electronic mail address Role

NERC EDS Environmental Information Data Centre

info@eidc.ac.uk

Distributor
OnLine resource
Protocol Linkage Name
https://data-package.ceh.ac.uk/data/50f4344e-a79a-4e1f-a9ee-e7985ed847cd

Download the data

OnLine resource
Protocol Linkage Name
https://data-package.ceh.ac.uk/sd/50f4344e-a79a-4e1f-a9ee-e7985ed847cd.zip

Supporting information

Hierarchy level
Dataset
Other

dataset

Conformance result

Title

Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services

Date (Publication)
2010-12-08
Statement

Surface water was collected via grab sampling at 23 sites across loch, river, and fish farm locations. In situ parameters were measured immediately using a HACH HQ4300 multimeter with calibrated pH, conductivity, and dissolved oxygen probes. Vacuum filtration units and portable pumps were used for sample processing. Samples were transported to the lab within 6 hours for processing. Nutrient concentrations were measured using segmented flow analysis; DOC, TIC, and TDN by thermal oxidation and chemiluminescence; metals and REEs by ICP-MS and ICP-OES; δ18O via isotope mass spectrometry. Phytoplankton were quantified using flow cytometry; particulate analyses followed gravimetric and spectrophotometric methods. Units include: Temperature (°C), pH (unitless), DO (mg/L, % saturation), conductivity (mS/cm) Nutrients: µmol/L or µg/L (e.g. nitrate, phosphate) DOC/TIC/TDN: mg/L Metals: µg/L or ppm Particulates: mg/L Phytoplankton: cells/mL CFDOM indices: Raman units or unitless indices (FI, HIX, BIX) Raw readings were calibrated and corrected; fluorescence data were processed in R; compiled data include site metadata and documented exclusions. Calibrations, reference standards, replicates, blanks, and internal controls were used. Analytical QA procedures were followed across all labs. Some data are missing due to instrument errors or lost samples. Not all parameters were measured at all sites.

Metadata

File identifier
50f4344e-a79a-4e1f-a9ee-e7985ed847cd XML
Metadata language
English
Character set
8859 Part 1
Hierarchy level
Dataset
Hierarchy level name

dataset

Date stamp
2025-11-13T16:15:02
Metadata standard name
UK GEMINI
Metadata standard version

2.3

Metadata author
Organisation name Individual name Electronic mail address Role
NERC EDS Environmental Information Data Centre

info@eidc.ac.uk

Point of contact
 
 

Overviews

Spatial extent

thumbnail

Keywords

GEMET - INSPIRE themes, version 1.0

Hydrography


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