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Observational data and model output for sediment nutrient cycling at Patagonian fjords

Glacier meltwater supplies a significant amount of silicon (Si) and iron (Fe) sourced from weathered bedrock to downstream ecosystems. However, the extent to which these essential nutrients reach the ocean is regulated by the nature of the benthic cycling of dissolved Si and Fe within fjord systems, given the rapid deposition of reactive particulate fractions at fjord heads. The dataset is used to examine the benthic cycling of the two nutrients at Patagonian fjord heads through geochemical analyses of sediment pore waters and reaction-transport modeling for Si. The dataset contains: (i) pore water redox-sensitive nitrate (NO3-) and dissolved manganese (DMn) concentration data, nutrient dissolved silicon (DSi) and iron (DFe) concentration and isotope data (delta30 Si, delta56 Fe); (ii) mild alkaline leachable (Si-Alk) and acid leachable (Si-HCl) sediment silica content and isotope data; and (iii) reaction transport model output for the benthic cycling of Si. The pore water and sediment samples were collected from four sites: SJ (48.228o S, 73.502o W, 106 m depth), SH (47.679 S, 73.715 W, 203 m depth), SP (48.179 S, 73.347 W, 248 m depth) and SB (47.787 S, 73.610 W, 151 m depth) in the Baker-Martinez Fjord Complex on the research vessel Sur-Austral in February 2017.





Funded by NERC-CONICYT grant NE/P003133/1-PII20150106.

Simple

Date (Creation)
2022-06-27
Date (Revision)
2022-06-27
Date (Publication)
2022-06-27
Date (released)
2022-06-27
Edition

1.0

Unique resource identifier
https://doi.org/10.5285/5af9e5cf-657d-4640-8ff3-dd3ec2f43367
Codespace

doi

Unique resource identifier
GB/NERC/BAS/PDC/01647
Codespace

https://data.bas.ac.uk/

Unique resource identifier
NE/P003133/1
Codespace

award

Other citation details

Please cite this item as: Ng, H., Hawkings, J., Wadham, J., Hendry, K., Conway, T., Bertrand, S., Sieber, M., Summers, B., Freitas, F., Ward, J., Pryer, H., & Arndt, S. (2022). Observational data and model output for sediment nutrient cycling at Patagonian fjords (Version 1.0) [Data set]. NERC EDS UK Polar Data Centre. https://doi.org/10.5285/5af9e5cf-657d-4640-8ff3-dd3ec2f43367

Credit

No credit.

Status
Completed
Point of contact
Organisation name Individual name Electronic mail address Role
University of Bristol Ng, Hong Chin Author
University of Pennsylvania Hawkings, Jon R. Author
University of Bristol Wadham, Jemma L. Author
British Antarctic Survey Hendry, Katharine R. Author
University of South Florida Conway, Tim M. Author
Ghent University Bertrand, Sebastien Author
University of South Florida Sieber, Matthias Author
University of South Florida Summers, Brent A. Author
University of Bristol Freitas, Felipe S. Author
University of Bristol Ward, James P.J. Author
University of Cambridge Pryer, Helena V. Author
Universite Libre de Bruxelles Arndt, Sandra Author
NERC EDS UK Polar Data Centre

PDCServiceDesk@bas.ac.uk

Point of contact
Maintenance and update frequency
As needed
Maintenance note
Completed
Global Change Master Directory (GCMD) Science Keywords
  • EARTH SCIENCE > Oceans > Coastal Processes > Fjords
  • EARTH SCIENCE > Oceans > Ocean Chemistry > Nutrients
  • EARTH SCIENCE > Oceans > Ocean Chemistry > Stable Isotopes
Theme
  • Early diagenesis

  • fjord

  • nutrient cycling

  • reaction transport model

  • stable isotopes

Place
  • Patagonia, Baker-Martinez Fjord Complex Chile

GEMET - INSPIRE themes, version 1.0

  • Oceanographic geographical features
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no limitations to public access
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no limitations
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Open Government Licence v3.0
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Data released under Open Government Licence V3.0:

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url

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Language
English
Character set
UTF8
Topic category
  • Environment
  • Oceans
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Begin date
2018-01-18
End date
2020-11-28
Supplemental Information

It is recommended that careful attention be paid to the contents of any data, and that the author be contacted with any questions regarding appropriate use. If you find any errors or omissions, please report them to polardatacentre@bas.ac.uk.

Title

European Petroleum Survey Group (EPSG) Geodetic Parameter Registry

Date (Publication)
2008-11-12
Cited responsible party
Organisation name Individual name Electronic mail address Role

European Petroleum Survey Group

EPSGadministrator@iogp.org

Publisher
Unique resource identifier
urn:ogc:def:crs:EPSG::3031
Version

6.18.3

Distributor

Distributor contact
Organisation name Individual name Electronic mail address Role
NERC EDS UK Polar Data Centre

PDCServiceDesk@bas.ac.uk

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text/csv
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bytes

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25600
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WWW:LINK-1.0-http--link

https://ramadda.data.bas.ac.uk/repository/entry/show?entryid=5af9e5cf-657d-4640-8ff3-dd3ec2f43367

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Methodology:

Silicon and nitrate concentrations were measured with spectrophotometry. Dissolved iron concentration, manganese concentration, iron isotopes and silicon isotopes were measured with inductively coupled plasma-mass spectrometry.





The reaction transport model employed is the Biogeochemical Reaction Network Simulator. The model was run under steady state assumption.





Pore water data depth resolution: 5 cm - 15 cm



Sediment data depth resolution: 10 cm - 50 cm



Model data depth resolution: 0.1 cm - 1 cm

Data collection:

(1) Thermo Scientific X-Series 2 quadrupole inductively coupled plasma-mass spectrometer (dissolved iron and manganese concentration measurements)





(2) Thermo-Finnigan Neptune multicollector-inductively coupled plasma-mass spectrometer (silicon and iron isotope measurements)





(3) Maple computing environment version 2016.0 (compile inputs for reaction transport modeling)

Data quality:

The accuracies of the pore water elemental concentration and isotope analyses were assessed with measurements of standard solutions. Errors associated with sediment and pore water analyses were assessed with replicate measurements of samples and standards. Analytical errors for: (i) NO3- concentration is about 0.5%; (ii) dMn concentration and dFe concentration are 0.7% - 8.9%; (iii) DSi concentration is about 2.5%; (iv) Si-Alk content is 25%; (v) Si-HCl content is 15%; (vi) delta30 Si is 0.08 per-mille - 0.34 per-mille, and (vii) delta56 Fe is 0.04 per-mille - 0.08 per-mille. Model's best fit with observational data was determined by minimizing the root-mean-square error.

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File identifier
5af9e5cf-657d-4640-8ff3-dd3ec2f43367 XML
Metadata language
English
Character set
UTF8
Hierarchy level
Dataset
Hierarchy level name

dataset

Date stamp
2022-06-27
Metadata standard name

ISO 19115 Geographic Information - Metadata

Metadata standard version

ISO 19115:2003(E)

Metadata author
Organisation name Individual name Electronic mail address Role
NERC EDS UK Polar Data Centre

polardatacentre@bas.ac.uk

Point of contact
 
 

Overviews

Spatial extent

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Keywords

Early diagenesis fjord nutrient cycling reaction transport model stable isotopes
GEMET - INSPIRE themes, version 1.0

Oceanographic geographical features
Global Change Master Directory (GCMD) Science Keywords

EARTH SCIENCE > Oceans > Coastal Processes > Fjords EARTH SCIENCE > Oceans > Ocean Chemistry > Nutrients EARTH SCIENCE > Oceans > Ocean Chemistry > Stable Isotopes


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