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Southern Ocean Atmospheric Photochemistry Experiment 2 (SOAPEX-2): Atmospheric Constituents Concentration Measurements from Cape Grim, Tasmania

Southern Ocean Atmospheric Photochemistry Experiment 2 (SOAPEX-2) is primarily an experiment to study atmospheric cleansing by free radicals in extremely clean and slightly perturbed tropospheric air and focuses on a field campaign carried out at Cape Grim, Tasmania in January-February 1999. The dataset contains concentrations of atmospheric constituents such as halocarbons, hydrocarbons, methane, nitric oxide, and carbon monoxide. This dataset is public.



Oxidation of almost all trace gases released into the atmosphere is initiated by hydroxyl (OH) radicals, produced mainly from the action of near-UV light on ozone in the presence of water vapour. Increasing evidence suggests that the oxidative capacity of the troposphere has been perturbed in recent years due to the emission of gases such as methane, carbon monoxide, non-methane hydrocarbons and nitrogen oxides from man-made sources. These perturbations may be causing changes in the natural atmospheric composition, for instance increasing tropospheric levels of the greenhouse gas ozone, which has important consequences for climate and human health. It is also possible that the rates of oxidation of gases such as methane, and production of sulphate aerosols from the oxidation of sulphur dioxide, have been modified. Taken together a change in the oxidative capacity of the atmosphere has many consequences for the long-term stability of the Earth's climate.



SOAPEX-2 builds upon the success of the original SOAPEX-I experiment conducted at Cape Grim in January/February 1995 which resulted in the publication of several papers to the literature on the relationship between concentrations of peroxy radicals and uv light levels in different NOx concentration regimes, and the consequences for ozone production and loss in the marine boundary layer. SOAPEX-2 is a more complete experiment with the addition of atmospheric measurements of key new species including hydroxyl, hydroperoxyl, halogen oxide and nitrate radicals, non methane hydrocarbons, speciated aldehydes, PAN and halocarbons.



SOAPEX-2 involves four groups of tropospheric scientists from the UK and Australia, namely the Universities of East Anglia, Leeds and Leicester along with CSIRO (Commonwealth Scientific Research Organisation), Melbourne.



The clean air photochemistry experiment is an essential prerequisite for experiments carried out in more polluted atmospheres. The data obtained is allowing rigorous testing of basic mechanisms which describe the behaviour of free radical concentrations at differing light levels, water vapour and nitrogen oxide concentrations, etc. The measurements performed in this project are expected to yield valuable information on chemical changes that are affecting the oxidative capacity of the global troposphere and, therefore, the rate at which the global atmosphere can cleanse itself of pollutants. The measurements are also highly relevant to the situation in more polluted atmospheres, where increased levels of confidence in our understanding of atmospheric chemistry is an essential prerequisite to any legislation designed to reduce regional and global pollution.



The specific objectives of SOAPEX-2 are:

* To quantitatively test fast photochemical theory in clean air.

* To examine perturbations from the baseline situation in polluted continental air containing more complex mixtures of free radical sources and sinks

* Investigation of the balance between tropospheric O3 production and destruction in differing NOx regimes

* A test of instrumental performance

* Testing of models used to simulate chemical processes in the lower atmosphere which are deficient in their description of boundary layer processes

Simple

Date (Publication)
1987-12-10T02:20:33
Date (Creation)
1987-12-10T02:20:33
Citation identifier
https://catalogue.ceda.ac.uk/uuid/a266f328ead407624dde4bb5c9e2e6a2
Citation identifier
NCAS British Atmospheric Data Centre (NCAS BADC) / a266f328ead407624dde4bb5c9e2e6a2
Point of contact
Organisation name Individual name Electronic mail address Role

Unavailable

Allan, Beverly

Unavailable

Author

Unavailable

Ayers, G.

Unavailable

Author

Unavailable

Baker, Jon

Unavailable

Author

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Brough, N.

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Author

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Carpenter, Lucy Jane

Unavailable

Author

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Creasey, David J.

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Author

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Fraser, P.

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Author

Unavailable

Galbally, Ian

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Author

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Gillett, R.

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Author

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Heard, Dwayne E.

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Author

Unavailable

Kivlighon, Loretta

Unavailable

Author

Unavailable

Kochhar, M.

Unavailable

Author

Unavailable

Krummel, P.

Unavailable

Author

Unavailable

Lee, James D.

Unavailable

Author

Unavailable

Lewis, Alastair C.

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Author

Unavailable

Meyer, M.

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Author

Unavailable

Mills, Graham

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Author

Unavailable

Monks, Paul S.

Unavailable

Author

Unavailable

Pilling, Michael J.

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Author

Unavailable

Salisbury, Gavin

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Author

Unavailable

Steele, P.

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Author

Unavailable

Sturrock, Georgina

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Author

Unavailable

Weeks, Ian

Unavailable

Author

NCAS British Atmospheric Data Centre (NCAS BADC)

badc@rl.ac.uk

Custodian

NCAS British Atmospheric Data Centre (NCAS BADC)

badc@rl.ac.uk

Distributor

NCAS British Atmospheric Data Centre (NCAS BADC)

badc@rl.ac.uk

pointofContact

NCAS British Atmospheric Data Centre (NCAS BADC)

badc@rl.ac.uk

Publisher
Maintenance and update frequency
Unknown
Update scope
Series
Keywords
  • SOAPEX-2

  • air pollution

  • in-situ

  • airborne

  • ship

  • balloon

GEMET - INSPIRE themes, version 1.0

  • atmospheric conditions

Access constraints
Other restrictions
Other constraints
Please contact the data centre for assistance on accessing data from this dataset collection.
Use constraints
Other restrictions
Other constraints
Under the following licence http://www.nationalarchives.gov.uk/doc/open-government-licence/version/3/, appropriate use of these data may fall under any use. This message is intended as guidance, always read the full licence. When using these data you must cite them correctly using the citation given on the CEDA Data Catalogue record.
Spatial representation type
Grid
Language
English
Topic category
  • Climatology, meteorology, atmosphere
N
S
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Begin date
1999-01-01T00:00:00
End date
1999-02-28T00:00:00
Unique resource identifier
WGS 84
Distribution format
Name Version

Contact data centre for format details.

Distributor contact
Organisation name Individual name Electronic mail address Role

NCAS British Atmospheric Data Centre (NCAS BADC)

badc@rl.ac.uk

Distributor
OnLine resource
Protocol Linkage Name
https://catalogue.ceda.ac.uk/uuid/a266f328ead407624dde4bb5c9e2e6a2

CEDA Data Catalogue Page

OnLine resource
Protocol Linkage Name
https://artefacts.ceda.ac.uk/badc_datadocs/soapex/tables.html

Methodology and Approach

OnLine resource
Protocol Linkage Name
https://artefacts.ceda.ac.uk/badc_datadocs/soapex/imgs/

BADC Doc: SOAPEX Photo Gallery

OnLine resource
Protocol Linkage Name
https://artefacts.ceda.ac.uk/badc_datadocs/soapex/soapex_a.pdf

Taking the air CSIRO Publication on SOAPEX

Hierarchy level
Series

Conformance result

Title

Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services

Date (Publication)
2010-12-08
Statement

Please see data lineage statements for each dataset within this collection for data lineage details.

Metadata

File identifier
a266f328ead407624dde4bb5c9e2e6a2 XML
Metadata language
English
Character set
UTF8
Hierarchy level
Series
Hierarchy level name

series

Date stamp
2026-01-12T03:27:07
Metadata standard name
UK GEMINI
Metadata standard version

2.3

Metadata author
Organisation name Individual name Electronic mail address Role

NCAS British Atmospheric Data Centre (NCAS BADC)

badc@rl.ac.uk

Point of contact
 
 

Overviews

Spatial extent

thumbnail

Keywords

GEMET - INSPIRE themes, version 1.0

atmospheric conditions


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